Get Advances in Heterocyclic Chemistry, Vol. 95 PDF

By Alan Katritzky

ISBN-10: 0123742722

ISBN-13: 9780123742728

The definitive serial within the box - considering that 1960. * offers up to date fabric on a quick transforming into and hugely topical topic quarter * comprises the most recent study overlaying a large choice of heterocyclic subject matters * Written via major specialists and designed as a guide for college kids and and educational researchers.

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Additional resources for Advances in Heterocyclic Chemistry, Vol. 95

Example text

By Grignard Reagents . . . . . . . . . . . . . . . . . . . C. By Secondary Amines and Phenols . . . . . . . . . . . . . . . XIV. Oxidation. . . . . . . . . . . . . . . . . . . . . . . . . A. With Molecular Oxygen . . . . . . . . . . . . . . . . . . . B. With Bromine or Iodine-Potassium Iodide . . . . . . . . . . . . C. With Ozone. . . . . . . . . . . . . . . . . . . . . . . D. With Hydrogen Peroxide or 3-Chloroperbenzoic Acid.

A. By Activated Carbon Compounds . . . . . . . . . . . . . . . B. By Grignard Reagents . . . . . . . . . . . . . . . . . . . C. By Secondary Amines and Phenols . . . . . . . . . . . . . . . XIV. Oxidation. . . . . . . . . . . . . . . . . . . . . . . . . A. With Molecular Oxygen . . . . . . . . . . . . . . . . . . . B. With Bromine or Iodine-Potassium Iodide . . . . . . . . . . . .

O R Me R N O [Sec. B N H2N(CH2)n NH2 (146) H Ph H H N Me N N N EtOH/ ∆ R (CH2)n Me N O O N Ph Ph (145) (147) (a) R = Ph, (b) R = CH2C(Me)3, (c) CH(Ph)2, (d) n = 2, (e) n = 3, (f) R = Ph, n = 2, (g) R = Ph, n = 3, (h) R = Ph, n = 4, (i) R = CH2C(Me)3, n = 2, (j) R = CH2C(Me)3, n = 3, (k) R = CH2C(Me)3, n = 4, (l) R = CH(Ph)2, n = 2, (m) R = CH(Ph)2, n = 3, (n) n = 4 Scheme 39 Ph H Me N N H2N S O N N H Ph O Me Ph N O N H + (149) H H2N MeOH /MeCO2H N NH2 ∆ S Ph Ph H Me N N (148) H2N S HO N N Ph 2 R (150) R1 R3 N 1 O N N Ph H 2 3 (a) R = Me, R = Ph, R = NHC(S)SMe (b) R1 = Me, R2 = Ph, R3 = NHCOPh (c) R1 = Me, R2 = Ph, R3 = NHC(S)NH2, (d) R1 = R2 = Me, R3 = NHC(S)SMe (151) Scheme 40 photoisomerization from the enol to the keto form.

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Advances in Heterocyclic Chemistry, Vol. 95 by Alan Katritzky


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