Download e-book for iPad: Advances in Catalysis, Vol. 16 by D.D. Eley, Herman Pines, Paul B. Weisz (Eds.)

By D.D. Eley, Herman Pines, Paul B. Weisz (Eds.)

ISBN-10: 0120078163

ISBN-13: 9780120078165

(from preface)The airplane, the printing plant, and the meteorological station, are each one structures containing many machines. The mode of co-action is sort of advanced and extremely specific—in each one case reaching a selected over-all outcome. to check or describe anybody of those structures, we might continue to research this complexity of interplay by means of taking without any consideration the ''simple'' lifestyles of the weather comparable to the airplane engine, the printing computer, the chronometer, and so forth. after all, each one of those is itself a classy mechanism, containing many ''simpler'' parts, like wheels, rods, pulleys, and so on. To a wide quantity the weather usually are not multiple, however the mode of interaction is back complicated, and differs in each one computing device achieve its particular goal.

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It will be demonstrated that by careful selection of model compounds, such as olefins and alcohols, it is possible to throw light on the catalytic action of alumina and to reveal the presence of active catalytic sites. Steric effects, molecular rearrangements, anchimeric assistance, and the use of tracer techniques have provided useful information about the nature of catalytic sites of aluminas and have led to a unified mechanism of their action. 111. Early Mechanisms and Observations I n his chemical autobiography, V.

Iarael . I1. Purpose .......................................................... I11. Early Mechanisms and Observations .................................. I Introduction . Page 49 IV Nature of Alumina Catalysts ........................................ V Isomeriaation Following Dehydration .................................. A. Cyelohexanol ................................................... B I-Butanol ..................................................... VI Steric Course of Dehydration ........................................

The hydrogen atom on carbon-3 cis to H, is in a different environment than the hydrogen atom of carbon-3 trans to H,; this nonequivalence is amply demonstrated by the NMR spectra of the n-ally1 complexes. VI. Double-Bond lsomerization in Olefins Double-bond migration in olefins necessitates the making and breaking of carbon-hydrogen bonds. * The detailed mechanism of specific hydrogen transfer reactions will be explored in subsequent sections. Only a few years ago transition metal hydrides were a rarity.

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Advances in Catalysis, Vol. 16 by D.D. Eley, Herman Pines, Paul B. Weisz (Eds.)


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